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2010-02-22 - Article/Dans un journal avec peer-review - Anglais - 10 page(s)

Denis Laurent, Marsal Philippe, Olivier Yoann , Godfroid Thomas, Lazzaroni Roberto , Hecq Michel, Cornil Jérôme , Snyders Rony , "Deposition of Functional Organic Thin Films by Pulsed Plasma Polymerization: A Joint Theoretical and Experimental Characterization" in Plasma Processes and Polymers, 7, 2, 172-181

  • Edition : Wiley - VCH Verlag GmbH & Co. (Germany)
  • Codes CREF : Chimie quantique (DI1321), Optique (DI1250), Chimie des solides (DI1316), Physique des plasmas (DI1233)
  • Unités de recherche UMONS : Chimie des matériaux nouveaux (S817), Chimie des interactions plasma-surface (S882)
  • Instituts UMONS : Institut de Recherche en Science et Ingénierie des Matériaux (Matériaux)
Texte intégral :

Abstract(s) :

(Anglais) The pulsed plasma polymerization of allylamine and cyclopropylamine is investigated to study the influence of the precursor chemical structure on the process selectivity toward the primary amine groups. Both systems are compared under similar mean powers injected in the discharges (Pmean). The results reveal an increase in the precursor fragmentation in the plasma and a decrease in the primary amine content of the film (%NH2) as Pmean increases. Nevertheless, below a critical Pmean value, different behaviors are observed depending on the precursor, cyclopropylamine being less plasma-fragmented than allylamine. As a result, plasma polymer films (PPF) synthesized from cyclopropylamine yield the largest %NH2. These results are rationalized with the help of theoretical calculations pointing to a preferential opening of the cyclopropylamine ring structure. Cyclopropylamine activation in the plasma can thus be achieved without fragmentation reactions, leading to a more efficient incorporation of the NH2 group of the precursor in the PPF.

Notes :
  • (Anglais) Lecture en ligne: http://onlinelibrary.wiley.com/doi/10.1002/ppap.200900131/pdf
  • (Anglais) Publié en ligne le 29 décembre 2009
Identifiants :
  • DOI : 10.1002/ppap.200900131