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2005-09-27 - Article/Dans un journal avec peer-review - Anglais - 6 page(s)

Ouarti N., Viville Pascal , Lazzaroni Roberto , Minatti E., Schapaccher M., Defieux A., Puteaux J.L., Borsali R., "Micellar Aggregation in Blends of Linear and Cyclic Poly(styrene-b-isoprene) Diblock Copolymers" in Langmuir, 21, 20, 9085-9090

  • Edition : American Chemical Society, Washington (DC)
  • Codes CREF : Chimie quantique (DI1321), Optique (DI1250)
  • Unités de recherche UMONS : Chimie des matériaux nouveaux (S817)
  • Instituts UMONS : Institut de Recherche en Science et Ingénierie des Matériaux (Matériaux)
Texte intégral :

Abstract(s) :

(Anglais) The morphology of micelles formed from blends of linear and cyclic poly(styrene-b-isoprene) (PS-b-PI) block copolymers has been investigated in solution using dynamic light scattering (DLS) and in thin solid deposits by atomic force microscopy (AFM) and transmission electron microscopy under cryogenic conditions (cryo-TEM). Micelles of the pure cyclic PS290-b-PI110 copolymers are wormlike cylindrical objects built by unidirectional aggregation of 33 nm wide sunflower micelles, while the linear block copolymer having the same volume fraction and molar mass forms spherical micelles 40 nm in diameter. The DLS, AFM, and cryo-TEM results consistently show that the addition of the linear copolymer (even for amounts as low as 5% w/w) to the cyclic copolymer rather favors the formation of spherical micelles at the expense of the cylindrical aggregates. Those results clearly show that the linear block copolymer chains can be used to stabilize the thermodynamically unstable elementary sunflower micelle. The thermal stability of the micelles (from the pure copolymers and from the blends) has been examined in solid deposits with in situ AFM measurements. Coalescence starts at about 70 °C, and the surface roughness shows a two-step decrease toward a fully homogeneous and flat structure.

Notes :
  • (Anglais) Publié le 26 août 2005
Identifiants :
  • DOI : 10.1021/la050935z