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2006-10-01 - Article/Dans un journal avec peer-review - Anglais - 12 page(s)

Paneva Dilyana, Mespouille Laetitia , Manolova Nevena, Degée Philippe, Rashkov Iliya, Dubois Philippe , "Comprehensive study on the formation of novel polyelectrolyte complexes from (quaternized) poly[2-dimethylamino)ethyl methacrylate] and poly[2-acryloylamido-2-methylpropane sodium sulfonate]" in Journal of Polymer Science. Part A-1, Polymer Chemistry, 44, 19, 5468-5479

  • Edition : Wiley Interscience, New York (NY)
  • Codes CREF : Chimie macromoléculaire (DI1315), Catalyses hétérogène et homogène (DI1334)
  • Unités de recherche UMONS : Matériaux Polymères et Composites (S816)
  • Instituts UMONS : Institut de Recherche en Science et Ingénierie des Matériaux (Matériaux)
Texte intégral :

Abstract(s) :

(Anglais) Polyelectrolyte complexes (PECs) have been prepared from well-defined (quaternized) poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) and high molecular weight poly(2-acrylamido-2-methylpropane sodium sulfonate) (PAMPSNa) after a thorough study of their viscometric properties. The effect of pH and quaternization degree of PDMAEMA on PECs stoichiometry has been examined. PEC-based materials have been characterized in terms of thermal stability, equilibrium swelling degree, and free/bound water composition. The stoichiometry and swellability of the physically crosslinked hydrogels obtained from fully quaternized PDMAEMA/PAMPSNa complexes do not depend on pH. In contrast, PECs made of non quaternized PDMAEMA and PAMPSNa are highly affected by pH, and could reversibly disintegrate at pH = 9. Partially quaternized PDMAEMA/PAMPSNa PECs exhibit intermediate properties and form stable loose structures in the whole investigated pH range. Finally, stable dispersions of PECs nanoparticles have been successfully produced from dilute solutions of the complementary polyelectrolytes. The nanoparticle average diameter as determined by dynamic light scattering proved to depend on the molar fraction of DMAEMA-based subunits and on the initial polyelectrolyte concentration.

Notes :
  • (Anglais) Publié le 21 août 2006
  • (Anglais) Lecture en ligne: http://onlinelibrary.wiley.com/doi/10.1002/pola.21594/pdf
Identifiants :
  • DOI : 10.1002/pola.21594